强度调制光电流谱研究TiO2悬浮体系光催化机理

用强度调制光电流谱在光电化学电池中研究TiO2粒子悬浮液体系中的光催化反应机理,将强度按正弦变化的调制光照射TiO2粒子悬浮液,产生随频率变化的光电流响应,收集在Pt电极上,得到了光电流响应复数平面图,其上半圆和下半圆分别代表光生空穴和光生电子的阴极还原和阳极氧化反应过程.根据阴极和阳极光电流的幅度及上下半圆的特征频率分析讨论了光催化反应的机理及外加电压和H2O2添加物的影响.     

Zeta电位法选择农药悬浮剂所需润湿分散剂

采用Zeta电位法对质量分数为20%的吡氟草胺悬浮剂所需润湿分散剂进行筛选,以激光粒度分布仪对实验体系的平均粒径(Dav)进行了验证。研究结果表明,除木质素磺酸钠以外,阴离子型润湿分散剂均可使体系的Zeta电位绝对值(│ζ│)达到40mV以上,体系较为稳定;阴离子型润湿分散剂NNO和MorwetD425复配后,相同使用量下体系的│ζ│较单一使用NNO和MorwetD425的大;当m(NNO):m(MorwetD425)=1:4,复配润湿分散剂的总质量分数为1%时,│ζ│达到最大值,颗粒平均粒径最小,热贮前后变化很小,体系达到最佳分散效果。因此,Zeta电位表征润湿分散剂在农药悬浮剂中的润湿分散性能与体系颗粒平均粒径的变化规律有良好的对应关系,故Zeta电位可作为表征润湿分散剂分散性能优劣的指标。     

磁悬浮演示实验仪

应用电磁学理论、机械力学以及电子技术自制了一套磁悬浮演示实验仪.该演示实验仪利用线性霍尔传感器来探测悬浮物体的位移,以达到控制悬浮的目的,添加数码管电压显示电路,定量显示电磁铁的磁性在悬浮过程中随悬浮物位置变化的自动调整,能精确而直观地演示磁悬浮的物理现象.该仪器结构简单、性能稳定、操作方便,能广泛用于课堂演示、课程设...     

半导体可饱和吸收镜实现固体激光器皮秒锁模的机理研究

对半导体可饱和吸收镜(SESAM)实现固体激光器皮秒锁模的机理进行了研究。通过对染料锁模介质和SESAM的结构对比,对SESAM皮秒锁模机理提出了一个新的解释。其在锁模激光器中充当锁模器件时,不仅仅是一个吸收体,同时也是一个增益介质。当腔内增益和损耗保持平衡时实现稳定的连续锁模。     

Properties of a vector soliton laser passively mode-locked by a fiber-based semiconductor saturable absorber operating in transmission

We experimentally demonstrate a passively mode-locked fiber laser employing a fiber-based semiconductor saturable absorber (SSA) operating in transmission. Polarization rotation locked vector solitons are observed in the laser. Due to the intrinsic dynamic feature of the laser, period-doubling of these vector solitons has also been observed. Furthermore, extra spectral sidebands are formed on the optical spectrum, caused by the energy exchange between the two orthogonal polarization components of the vector solitons. By careful reduction of the pump power together with fine adjustment to the cavity birefringence, period-one state can further be obtained. Additionally, the phase noise properties of the vector soliton fiber laser have also been characterized experimentally and analytically.     

Graphene-based passively Q-switched diode-side-pumped Nd:YAG solid laser

In this paper, a desirably simple, convenient and inexpensive saturable absorber mirror has been fabricated based on graphene, which has no wavelength selectivity. Moreover, there are no changes in the structure and characteristics of graphene. By inserting the graphene-PMMA SA mirror to the Nd: YAG laser, the shortest pulse width of 260 ns can be obtained with the single-pulse energy of about 8.32 μJ. The experimental results prove that our graphene-PMMA SA mirror is feasible and suitable for Q-switched lasers.     

Fabrication and electromagnetic wave absorption properties of amorphous Ni-P nanotubes

Amorphous Ni-P nanotubes are fabricated through electroless chemical deposition inside an anodic aluminum oxide template. The hysteresis loops of Ni-P nanotube arrays are each found to exhibit an unusual isotropic behaviour, which is believed to be due to the competition results between the shape anisotropy and the magnetostatic interaction among nanotubes. The dynamic dependence of permittivity on the frequency spectrum is fitted to the Lorentzian-type dispersion law. The permeability dispersion behaviours have been fitted based on the Kittel equation. Electromagnetic wave absorption properties of Ni-P nanotubes/paraffin composites with different values of thickness (t) are clearly shown by a three-dimensional graph. Furthermore, the bandwidths of composites with different "t" values can be well presented by a two-dimensional contour graph, which is a novel presentation form. The results show that the composites each have a good microwave absorption performance with t larger than 5.5 mm and with the frequency around 8 gigahertz.     

二苯酮类紫外线吸收剂衍生物的分子设计

UV-0为母体结构,设计了系列新型含氟衍生物,以增强二苯酮类紫外线吸收剂在涂层表面的含量,提高其抗紫外线性能. 为探讨含氟侧链的引入对几何构型和电子光谱等性质的影响,筛选新型紫外线吸收剂,采用量子化学密度泛函理论在B3LYP/6-31++G**水平上对标题化合物分子几何构型进行了优化和电子光谱研究. 计算结果表明：含氟侧链通过酯键连接时,随着侧链的增长,O17与环B之间的共轭作用减弱,分子共轭体系减小,对紫外线的吸收能力变弱;含氟侧链通过醚键连接时,其在230~290 nm、310~400 nm区间有更强的紫外线吸收能力,同时含氟侧链的长度对紫外吸收曲线的影响较小. 综合考虑衍生物的紫外线吸收能力和的表面富集能力,预测化合物Ⅴ最优.     

液体表面张力系数实验装置的改进

对现有吊环法液体表面张力系数测量仪的水平调节装置、吊环升降装置存在的不足进行了改进,在原有仪器上增加了液体加热装置,以便对不同温度下的液体表面张力系数进行测量,实验说明新的实验装置更加科学合理.通过实验对比得出:新的实验装置操作方便、实验误差小、重复性好,有推广价值.     

具有横向磁晶各向异性的钴纳米线的微波吸收性能

使用电化学脉冲沉积法制备了磁晶各向异性易磁化方向(c轴)垂直纳米线长轴方向的钴纳米线.受到磁晶各向异性、静磁相互作用等因素与形状各向异性相互竞争的结果,纳米线阵列的磁滞回线显示出较弱的磁各向异性.此外,在2—18 GHz频率范围内,纳米线/石蜡复合材料的介电色散谱的虚部在5 GHz处有一个主峰,在10 GHz附近有一个较弱的峰;德拜弛豫特性和材料的电导率对这两个峰的形成均有贡献.同时,其磁导率色散谱的虚部在频率为6.1 GHz处有一个主峰,在10 GHz以上有两个较微弱的峰. 前一个峰源于自 关键词： 钴纳米线 介电色散谱 磁导率色散谱 微波吸收剂